Citizen science reveals the current distribution of the new plant pest Aphis nerii in Slovakia

This paper presents the first record of the oleander aphid (Aphis nerii Boyer de Fonscolombe, 1841; Hemiptera: Aphididae) in Slovakia, and also one of the most northern record of this natural pest on the invasive common milkweed (Asclepias syriaca Linnaeus.; Apocynaceae) in Central Europe. Modern social media crowdsourcing has achieved comprehensive distribution data in the horticultural community, and a total of 35 new distribution sites were discovered in 28 Slovak settlements, one new site in Austria, and one in the Czech Republic. It was further established that the oleander aphid could survive in anthropogenic refuges during the winter months

Vertikálna migrácia taxónov vyšších rastlín v alpínskom pásme ako nový, akcelerujúci fenomén

Observed climate change, especially warming, is having significant impacts on the distribution of European flora and these impacts include uphill range shifts, as well as predict potential local and regional extinctions of species. This process can be also called as a vertical migration of species. The related research in subalpine and alpine belt of the European mountains brought several interesting results during the last 15 years, above all by the GLORIA initiative network and a project sUMMITDiv with repeated plant survey from 302 mountain summits across Europe and spanning 145 years of observation. A continent-wide acceleration in the rate of increase in plant species richness, with five times as much species enrichment between 2007 and 2016 as fifty years ago, between 1957 and 1966 has been confirmed (Steinbauer et al., 2018)

Nutrition, Body Weight and Deterioration of Familial Combined Hyperlipidemia

Lipid and apolipoprotein serum levels as a consequence of excessive nutrition in the overweight individuals with familial combined hyperlipidemia (FCHL) in comparison with the obese ones are studied only sporadically. In this study, the effect of overweight and obesity in subjects with FCHL on serum lipids and apolipoproteins was investigated. The participants were 36 overweight and 10 obese men. 17 normolipidemic healthy men served as the control group. The mean age of all subjects included was 49±9 years. Lipid and apolipoprotein serum levels were determined by standard methods. The increased body weight in overweight men with FCHL correlates with increased cholesterol and triacylglycerol serum levels (p<0.001), atherogenous ratio values, apolipoprotein serum levels – apo C-III, apo C-II and apo B100 (p<0.001) as well as decreased HDL cholesterol serum levels (p<0.05). Lipid metabolism in men with FCHL is deteriorated by a high energy intake and its low output. The overweight and not only obesity, in association with FCHL, is an important risk factor for premature development of ischemic events

Superabsorbent hydrogels made from bio-sourced butyrolactone monomer in aqueous solution

A new water-soluble monomer, sodium 4-hydroxy-4-methyl-2-methylene butanoate (SHMeMB), formed by saponification of the bio-derived monomer γ-methyl-α-methylene-γ-butyrolactone (MeMBL), was copolymerized with acrylamide (AM) in aqueous solution to make superabsorbent hydrogels with equilibrium degree of swelling in the range of 6700–59 000%, depending on monomer ratio and crosslink density. Mechanical strength and storage and loss moduli of the hydrogels were tunable over a wide range through adjustment of the comonomer composition and the crosslinker content. Monomer reactivity ratios of rSHMeMB = 0.12–0.17 and rAM = 0.95–1.10 were determined using copolymer compositions measured at low monomer conversion as well as by applying the integrated form of the Mayo-Lewis equation to fit the drift in comonomer composition with conversion. The reactivity of the SHMeMB : AM system was lower than that of the previously-studied SHMB : AM system, with sodium 4-hydroxy-2-methylene butanoate (SHMB) derived from a similar renewable monomer, α-methylene-γ-butyrolactone (MBL). The differences in reactivity were studied by pulsed laser polymerization coupled with size exclusion chromatography; the comonomer-averaged propagation rate coefficient of the SHMB : AM system was found to be more than double that of SHMeMB : AM, with first estimates for the SHMeMB and SHMB homopropagation rate coefficients of 25 and 165 L mol−1 s−1, respectively, at 60 °C. Despite its lower reactivity, SHMeMB offers advantages over SHMB due to its availability and as superior overall properties of the final hydrogels were achieved.European Regional Development Fund through project POLYFRIEND, within Hungary-Slovakia Cross-border Co-operation Programme [HUSK 1101/1.2.1/0209]; Slovak Academic Information Agency (SAIA) [VEGA 2/0158/17]; Natural Sciences and Engineering Research Council of Canada (NSERC

Full Information from Measured ADC Test Data using Maximum Likelihood Estimation

Abstract ADC testing is often done using sine wave excitation (see e.g. IEEE standard 1241). A sine wave is fitted to the measured data in least squares sense, and the residuals are analyzed further. In recent papers, it has been recognized that even more (and more precise) information can be extracted by the solution of the maximum likelihood equations. This is an improvement to the usual three-parameter and four-parameter fits. In this paper practical implementation of this algorithm is suggested. Then, theoretical background is overviewed. Further investigations lead to the statement that the same principle can be extended to any measurement which uses an excitation signal which can be described with a few parameters. A candidate for this is an exponential signal, with 3 parameters: e.g. start value, end (steady-state) value, and time constant. The maximum likelihood (ML) equations yield a solution for these too, more accurate than least squares (LS) fitting. Reasonable approximations make the ML problem solvable in practice

Impact of secondary succession in abandoned fields on some properties of acidic sandy soils

Abandonment of agricultural lands in recent decades is occurring mainly in Europe, North America and Oceania, and changing the fate of landscapes as the ecosystem recovers during fallow stage. The objective of this study was to find the impact of secondary succession in abandoned fields on some parameters of acidic sandy soils in the Borská nížina lowland (southwestern Slovakia). We investigated soil chemical (pH and soil organic carbon content), hydrophysical (water sorptivity, and hydraulic conductivity), and water repellency (water drop penetration time, water repellency cessation time, repellency index, and modified repellency index) parameters, as well as the ethanol sorptivity of the studied soils. Both the hydrophysical and chemical parameters decreased significantly during abandonment of the three investigated agricultural fields. On the other hand, the water repellency parameters increased significantly, but the ethanol sorptivity did not change during abandonment. As the ethanol sorptivity depends mainly on soil pore size, the last finding could mean that the pore size of acidic sandy soils did not change during succession

Impact of climate, soil properties and grassland cover on soil water repellency

Numerous soil water repellency (SWR) studies have investigated the possible causes of this temporal phenomenon, yet there remains a lack of knowledge on the order of importance of the main driving forces of SWR in the context of changing environmental conditions under grassland ecosystems. To study the separate and combined effects of soil texture, climate, and grassland cover type on inducing or altering SWR, four sites from different climatic and soil regions were selected: Ciavolo (CI, IT), Cs´olyosp´alos (CSP, HU), Pwllpeiran (PW, UK), Sekule (SE, SK). The investigated parameters were the extent (determined by repellency indices RI, RIc and RIm) and persistence (determined by water drop penetration time (WDPT) and water repellency cessation time, WRCT) of SWR, as well as field water (Sw) and ethanol (Se) sorptivity, water sorptivity of hydrophobic soil state (Swh) water sorptivity of nearly wettable soil state (Sww) and field hydraulic conductivity (K). Our findings showed an area of land has a greater likelihood of being water repellent if it has a sandy soil texture and/or a high frequency of prolonged drought events. Water infiltration was positively correlated with all the sorptivities (r = 0.32–0.88), but was mostly negatively correlated with RI (r = – 0.54 at CI), WDPT (r = – 0.47 at CI) and WRCT (r = – 0.58 at CI). The importance of natural and synanthropized vegetation covers with regards to SWR was not coherent; moving to regions having coarser texture or moving to drier climatic zones led to higher risk of SWR conditions. Climate change has been predicted to lead to more frequent extreme weather events and prolonged dry periods across Europe, which will most likely increase the extent of SWR-affected areas and increase the role of SWR in water management of grassland ecosystems. Therefore, there is a need to determine SWR risk zones to prevent decreases in soil moisture content, soil fertility, carbon and nitrogen sink potentials, as well as biomass production of the related agro-ecosystems

Atom transfer radical polymerization of pyrrole-bearing methacrylate for production of carbonyl iron particles with conducting shell for enhanced electromagnetic hielding

The conducting polymer poly(2-(1H-pyrrole-1-yl)ethyl methacrylate (PPEMA) was synthesized by conventional atom transfer radical polymerization for the first time from free as well as surface-bonded alkyl bromide initiator. When grafted from the surface of carbonyl iron (CI) a substantial conducting shell on the magnetic core was obtained. Synthesis of the monomer as well as its polymer was confirmed using proton spectrum nuclear magnetic resonance (H-1 NMR). Polymers with various molar masses and low dispersity showed the variability of this approach, providing a system with a tailorable structure and brush-like morphology. Successful grafting from the CI surface was elucidate by transmission electron microscopy and Fourier-transform infrared spectroscopy. Very importantly, thanks to the targeted nanometer-scale shell thickness of the PPEMA coating, the magnetization properties of the particles were negligibly affected, as confirmed using vibration sample magnetometry. Smart elastomers (SE) consisting of bare CI or CI grafted with PPEMA chains (CI-PPEMA) and silicone elastomer were prepared and dynamic mechanical properties as well as interference shielding ones were investigated. It was found that short polymer chains grafted to the CI particles exhibited the plasticizing effect, which might be interesting from the magnetorheological point of view, and more interestingly, in comparison to the neat CI-based sample, it provided enhanced electromagnetic shielding of nearly 30 dB in thickness of 500 mu m. Thus, SE containing the newly synthesized CI-PPEMA hybrid particles also exhibited considerably enhanced damping factor and proper mechanical performance, which make the material highly promising from various practical application points of view.Ministry of Education, Youth and Sports of the Czech Republic-DKRVO [RP/CPS/2022/003]; Internal Grant Agency of Tomas Bata University in Zlin [IGA/CPS/2021/003]; Integrated Infrastructure Operational Programme - ERDF [313021T081]; Slovak Research and Development Agency [APVV-19-0338]; Slovak Grant Agency VEGA [2/0129/19]; Qatar University Grant [QUCG-CAM-22/23-504]RP/CPS/2022/003; Slovenská Akadémia Vied, SAV: 313021T081; Tomas Bata University in Zlin, TBU: IGA/CPS/2021/003; Qatar University, QU: QUCG-CAM-22/23-504; Agentúra na Podporu Výskumu a Vývoja, APVV: APVV-19-0338; Vedecká Grantová Agentúra MŠVVaŠ SR a SAV, VEGA: 2/0129/19; European Regional Development Fund, ERD

Polyethylene Glycol-Modified Poly(Styrene-co-Ethylene/Butylene-co-Styrene)/Carbon Nanotubes Composite for Humidity Sensing

Polymeric composites of the linear triblock copolymer poly(styrene-co-ethylene/butylene-co-styrene) grafted with maleic anhydride units (SEBS-MA) or MA modified by hydrophilic polyethylene glycol (PEG) and containing various amounts of multiwall carbon nanotubes (MWCNTs) as conducting filler—were prepared by solvent casting. The MWCNT surface was modified by a non-covalent approach with a pyrene-based surfactant to achieve a homogeneous dispersion of the conducting filler within the polymeric matrix. The dispersion of the unmodified and surfactant-modified MWCNTs within the elastomeric SEBS-MA and SEBS-MA-PEG matrices was characterized by studying the morphology by TEM and SAXS. Dynamical mechanical analysis was used to evaluate the interaction between the MWCNTs and copolymer matrix. The electrical conductivity of the prepared composites was measured by dielectric relaxation spectroscopy, and the percolation threshold was calculated. The prepared elastomeric composites were characterized and studied as humidity sensor. Our results demonstrated that at MWCNTs concentration slightly above the percolation threshold could result in large signal changes. In our system, good results were obtained for MWCNT loading of 2 wt% and an ~0.1 mm thin composite film. The thickness of the tested elastomeric composites and the source current appear to be very important factors that influence the sensing performance